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What is the current rate I could expect my employer to pay per km for using my private car for business (I have a Toyota Caldina). Thanks kaye

Assuming it's a 2.0 litre, the AA Calculation would be 65c per km. However, our calculations are based on cars between 3 - 5 years old where depreciation is a significant component, so if your car is older, the true rate may be less.
Also, while we calculate the running cost, any negotiation between employers and employees can be whatever the parties negotiate and agree upon.